碳纤维(CF)树脂基复合材料由于其良好的力学性能被应用于航天、航空、化工等领域,但由于CF表面呈惰性,与树脂基体界面结合性较差,限制了其力学性能的发挥。由微米尺度的CF与纳米尺度的碳纳米管(CNTs)复合而成的CNTs/CF多尺度增强体,可以改善复合材料的界面性能,有助于其力学性能的提升,是目前CF复合材料领域的研究热点。简单介绍了CNTs/CF多尺度增强体复合材料的研究进展,并阐述了未来的发展趋势。
Carbon fiber (CF) composite materials are widely used in aerospace,chemical industry,and other industries due to their good mechanical properties.However,due to the inertness of the CF surface,the poor combination with the substrate interface affects its overall mechanical properties.Carbon nanotubes (CNTs)/CF multiscale composite materials prepared from micro-scale carbon fibers and nano-scale carbon nanotubes can significantly improve their interface performance.The research progress of CNTs/CF multiscale reinforcement composite materials was introduced,and summarized the preparation methods.
[1] 董博.复合材料及碳纤维复合材料应用现状[J].辽宁化工,2013,42(5):552-562.
[2] Thostenson E T,Li W Z,Wang D Z,et al.Carbon nanotube/carbon fiber hybrid multiscale composites[J].Journal of Applied Physics,2002,91(9):6034-6037.
[3] Agnihotri P,Basu S,Kar K K.Effect of carbon nanotube length and density on the properties of carbon nanotube-coated carbon fiber/polyester composites[J].Carbon,2011,49(9):3098-3106.
[4] Lv P,Feng Y Y,Zhang P,et al.Increasing the interfacial strength in carbon fiber/epoxy composites by controlling the orientation and length of carbon nanotubes grown on the fibers[J].Carbon,2011,49(14):4665-4673.
[5] Singh C,Shaffer M S P,Windle A H.Production of controlled architectures of aligned carbon nanotubes by an injection chemical vapour deposition method[J].Carbon,2003,41:359-368.
[6] De Greef N,Zhang L,Magrez A,et al.Direct growth of carbon nanotubes on carbon fibers:effect of the CVD parameters on the degradation of mechanical properties of carbon fibers[J].Diamond and Related Materials,2015,51:39-48.
[7] De Greef N,Magrez A,Couteau E,et al.Growth of carbon nanotubes on carbon fibers without strength degradation[J].Physica Status Solidi(B),2012,249(12):2420-2423.
[8] Felisberto M,Tzounis L,Sacco L,et al.Carbon nanotubes grown on carbon fiber yarns by a low temperature CVD method:a significant enhancement of the interfacial adhesion between carbon fiber/epoxy matrix hierarchical composites[J].Composites Communications,2017,3:33-37.
[9] Lee G,Youk J H,Lee J,et al.Low-temperature grafting of carbon nanotubes on carbon fibers using a bimetallic floating catalyst[J].Diamond and Related Materials,2016,68:118-126.
[10] Islam M S,Deng Y,Tong L,et al.Grafting carbon nanotubes directly onto carbon fibers for superior mechanical stability:towards next generation aerospace composites and energy storage applications[J].Carbon,2016,96:701-710.
[11] Anthony D B,Sui X,Kellersztein I,et al.Continuous carbon nanotube synthesis on charged carbon fibers[J].Composites Part A:Applied Science and Manufacturing,2018,112:525-538.
[12] Zheng L,Wang Y,Qin J,et al.Scalable manufacturing of carbon nanotubes on continuous carbon fibers surface from chemical vapor deposition[J].Vacuum,2018,152:84-90.
[13] 梅辉,肖珊珊.电泳沉积时间和热处理对碳纳米管增强C/SiC复合材料力学性能的影响[J].硅酸盐学报,2014,32(12):1479-1486.
[14] Cho J,Konopka K,Roniatowski K,et al.Characterisation of carbon nanotube films deposited by electrophoretic deposition[J].Carbon,2009,47(1):58-67.
[15] Bekyarova E,Thostenson E T,Yu A,et al.Multiscale carbon nanotube-narbon fiber reinforcement for advanced epoxy composites[J].Langmuir:the ACS Journal of Surfaces and Colloids,2007,23(7):3970-3974.
[16] Deng C,Jiang J,Liu F,et al.Influence of carbon nanotubes coatings onto carbon fiber by oxidative treatments combined with electrophoretic deposition on interfacial properties of carbon fiber composite[J].Applied Surface Science,2015,357:1274-1280.
[17] An Q,Rider A N,Thostenson E T.Electrophoretic deposition of carbon nanotubes onto carbon-fiber fabric for production of carbon/epoxy composites with improved mechanical properties[J].Carbon,2012,50(11):4130-4143.
[18] Jiang J,Xu C,Su Y,et al.Influence of carbon nanotube coatings on carbon fiber by ultrasonically assisted electrophoretic deposition on its composite interfacial property[J].Polymers (Basel),2016,doi:10.3390/polym8080302.
[19] Li L,Liu W,Yang F,et al.Interfacial reinforcement of hybrid composite by electrophoretic deposition for vertically aligned carbon nanotubes on carbon fiber[J].Composites Science and Technology,2020,187:107946页码.
[20] Zhang S,Liu W B,Hao L F,et al.Preparation of carbon nanotube/carbon fiber hybrid fiber by combining electrophoretic deposition and sizing process for enhancing interfacial strength in carbon fiber composites[J].Composites Science and Technology,2013,88:120-125.
[21] Liu Yuting,Yao Tingting.Laser welding of carbon nanotube networks on carbon fibers from ultrasonic-directed assembly[J].Materials Letters,2019,236:244-247.
[22] He X,Zhang F,Zhang W S,et al.Preparation of a carbon nanotube/carbon fiber multi-scale reinforcement by grafting multi-walled carbon nanotubes onto the fibers[J].Carbon,2007,45(13):2559-2563.
[23] Laachachi A,Vivet A,Nouet G,et al.A chemical method to graft carbon nanotubes onto a carbon fiber[J].Materials Letters,2008,62(3):394-397.
[24] Wu Z,Meng L,Liu L,et al.Chemically grafting carbon nanotubes onto carbon fibers by poly (acryloyl chloride) for enhancing interfacial strength in carbon fiber/unsaturated polyester composites[J].Fibers and Polymers,2014,15(3):659-663.
[25] Lv Yongqiang,Peng Chunzheng.Chemically grafting carbon nanotubes onto carbon fibers for enhancing interfacial strength in carbon fiber/HDPE composites[J].Surface and Interface Analysis,2018,50(5):552-557.
[26] Peng Q,He X,Li Y,et al.Chemically and uniformly grafting carbon nanotubes onto carbon fibers by poly(amidoamine) for enhancing interfacial strength in carbon fiber composites[J].Journal of Materials Chemistry,2012,22(13):5928-5931.
[27] Chen B,Li X,Yang J,et al.Enhancement of the tribological properties of carbon fiber/epoxy composite by grafting carbon nanotubes onto fibers[J].RSC Advances,2016,6(55):49387-49394.
[28] Chen Q,Peng Q,Zhao X,et al.Grafting carbon nanotubes densely on carbon fibers by poly (propylene imine) for interfacial enhancement of carbon fiber composites[J].Carbon,2020,158:704-710.
[29] Wu G,Liu L,Huang Y.Grafting of active carbon nanotubes onto carbon fiber using one-pot aryl diazonium reaction for superior interfacial strength in silicone resin composites[J].Composites Communications,2019,13:103-106.
基金资助
青海省自然科学基金项目(2018ZJ923Q)
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